All That Matters

Understanding the properties of something chaotic such as a bowl of spaghetti may seem a daunting task. But that’s what Garry Rumbles from the National Renewable Energy Laboratory in the USA, Natalie Stingelin from Imperial College London in the UK, and coworkers are trying to do. With success. They study polymers – long spaghetti-like molecules made of repeating atomic subunits – and have now uncovered how the microstructure of these polymers controls the behaviour of optically generated electrical charges in such a tangled molecular web, with important implications for the design of electronic devices.

The physical properties of polymers depend a lot on the length of the molecules as a whole, the atomic make-up of their structural units and the physical interactions between the individual strings. That’s why polymers come in so many forms, from hard plastics to stretchable synthetic rubbers. And what Stingelin and Rumbles now show is that also their electronic properties depend not only the chemical make-up of the polymers, but also the details of their structure and their molecular weight. This has dramatic consequences for the search of new polymers for various optical and electronic applications, says Stingelin. “Are there otherwise wonderful polymers out there that were cast aside because their creators tested the wrong molecular weight? We think it’s quite possible.”

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The past year has been a great year for science with major advances in several areas. Too many exciting results to mention here. Instead, to reflect about the past year I have chosen a representative paper for each month of the year that I hope can serve as an example of the great science going on in a number of research fields. Of course, this is a highly subjective and personal collection, and indeed there might be others worth mentioning. But the aim was also to provide a balanced overview of the year that covers a variety of topics.

Of course, if you have an exciting paper to add, please feel free to use the comments section below to let us know!

Anyway, enough said, here are some of my highlights from the past year:

Simulations of electronic excitations in an iron-based superconductor. Image by Oak Ridge National Laboratory via flickr.

JANUARY – iron-based superconductors

Since they were discovered in 2008, iron-based superconductors, the pnictides, have been one of the hottest topics in condensed matter physics. Part of their appeal stems from the fact that they are based on iron, which is a magnetic element. Normally, magnets and superconductivity exclude each other.

The iron-based compounds have a similar crystal structure as the so-called cuprates, which are the materials with the highest superconducting temperatures known. The mechanism for these high-temperature superconductors is unknown, and studying the iron-based superconductors may also be relevant to the understanding of the cuprates.

This paper published in Science shows for the first time that the electrons in the iron-based superconductors show a periodic arrangement that is different to the periodicity of the atoms in the crystal. Similar observations have been made in the cuprates, and their understanding is considered important to the mechanism of high-temperature superconductivity.

Chuang, T., Allan, M., Lee, J., Xie, Y., Ni, N., Bud’ko, S., Boebinger, G., Canfield, P., & Davis, J. (2010). Nematic Electronic Structure in the “Parent” State of the Iron-Based Superconductor Ca(Fe1-xCox)2As2 Science, 327 (5962), 181-184 DOI: 10.1126/science.1181083

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Solar energy is obviously one of the key renewable energy resources available to us. At the same time researchers are hitting against a glass ceiling. A famous 1961 paper by William Shockley (who co-invented the transistor) and Hans Queisser comes to the conclusion that for a semiconductor such as silicon the maximum conversion efficiency of solar energy into electricity will never be more than about 30%.

Dye-sensitized solar cells. A design similar to these solar cells is now used to demonstrate the creation and extraction of multiple charge carriers per photons.

One reason for this limit is that each light particle only excites one electron. Even if the electron has enough energy to excite two electrons, all this energy is lost and only one electron is excited. And this is the case for pretty much all present commercial solar cell technology. Fortunately, however, there are possible exceptions. Bruce Parkinson and colleagues from the University of Wyoming in the USA have now built a photovoltaic cell that at certain wavelengths of light can generate more than one electron per photon of light. Their approach promises to beat the Shockley-Queisser limit and could lead to solar cells with considerably enhanced efficiency.

In silicon and other semiconductors, if a photon excites an electron all excess energy is predominantly lost as heat. Of course, there are attempts to harvest the heat generated in solar cells, and such approaches could beat the Shockley-Queisser limit. And so could nanostructured materials that use for example plasmonic effects. But a more direct solution would be if the excess energy could be used to excite more than one electron in the first place.

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This week my colleagues at Nature Chemistry landed an impressive scoop, the publication of a paper by Michael Strano and colleagues from MIT on self-regenerating solar cells.

The performance of any kind of solar cell tends to degrade over time. This is particularly the case for organic solar cells, where sunlight can easily destroy the structure of the molecules used. Natural light-harvesting processes have a similar problem, for example during photosynthesis. The way plants solve this problem is through a self-repair mechanism.

Schematic of the regenerating solar cell consisting of light-absorbing proteins, lipid disks and carbon nanotubes. Reprinted by permission from Macmillan Publishers Ltd. Nature Chemistry, advance online publication (2010)

Taking cues from such self-regeneration strategies, Strano and colleagues use a concept that is surprisingly simple. They prepare a solution containing carbon nanotubes, bacterial light-harvesting proteins and discs made from lipid molecules — the structural components that form the membrane of cells. Once the surfactant that keeps all these molecules separate is removed the molecules assemble themselves: the proteins bind to the lipids, which then attach to the carbon nanotubes. No assembly required.

During solar cell operation sunlight is absorbed by the proteins and creates electronic charges that are transported along the carbon nanotubes to the electrical contacts of the solar cell. To regenerate the proteins damaged by the sunlight, surfactant is added again, along with a small quantity of new proteins to replace damaged molecules. This dissolves the structure. But once the surfactant is removed the molecules reassemble, fully repaired.

In the study, the solar cells ran on a 40 hour cycle: 32 hours of operation, followed by 8 hours regeneration. Despite so many hours of regeneration overall cell performance was up by a remarkable 300% in comparison to cells that are not regenerated. And this could be just the beginning. At the moment, as soon as the cells are turned on they lose about 60% efficiency within the first hour or so of operation. Delaying the onset of degradation or finding a more efficient way of regeneration should lead to further enhancements. But who knows, nature may have a solution to this problem, too.

Reference:
Ham, M., Choi, J., Boghossian, A., Jeng, E., Graff, R., Heller, D., Chang, A., Mattis, A., Bayburt, T., Grinkova, Y., Zeiger, A., Van Vliet, K., Hobbie, E., Sligar, S., Wraight, C., & Strano, M. (2010). Photoelectrochemical complexes for solar energy conversion that chemically and autonomously regenerate Nature Chemistry DOI: 10.1038/NCHEM.822

Photo by Scott Robinson (Clearly Ambiguous) via flickr.

Solar energy is a huge market and any improvement to the efficiency of solar cells has a significant impact. In 2008, worldwide photovoltaic solar energy production was about 5 gigawatts, and this is expected to rise to 15 gigawatts in 2015. To put this figure in context, a nuclear reactor produces around 1 to 1.5 gigawatts of electricity.

The overall conversion efficiency of the best solar cell devices, with complex designs that include multiple materials, reaches up to about 50%. For more common silicon-based solar cells efficiencies are around 20%, although commercial photovoltaic panels achieve even less than that. Any enhancement in solar cell efficiency, whether it is in terms of costs or in terms of efficiency, is therefore highly desirable and significant. If all photovoltaic cells that produce those 5 gigawatts of energy were only 5% more efficient, for example with 21% conversion efficiency instead of 20%, it would result in an increase in energy production equivalent to about 250 megawatts.

Another issue is cost. Bulk solar cells are better at catching more sunlight, but use more material and therefore cost a lot more than thin-film films. Albert Polman, Harry Atwater and colleagues have now developed a solar cell design that enhances the power efficiency of thin solar cells. In their study published in Optics Express they are able to enhance the efficiency of a 340 nanometer thick silicon solar cell by 27% when compared to a regular thin-film cell.

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